ISSN: 2375-3919
American Journal of Materials Research  
Manuscript Information
 
 
Effect of the Compatibilizers on Polycarbonate (PC) /Acrylonitrile-Butadiene-Styrene (ABS) Blend
American Journal of Materials Research
Vol.1 , No. 3, Publication Date: Oct. 8, 2014, Page: 48-52
1563 Views Since October 8, 2014, 5580 Downloads Since Apr. 14, 2015
 
 
Authors
 
[1]    

Yanqin Liu, The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

[2]    

Haoxue Li, Henan Mechanical and Electrical Engineering College, Henan, China.

[3]    

Xuejia Ding, The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

[4]    

Jieke Zhu, The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

[5]    

Long Zhang, The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

[6]    

Wei Pan, The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

[7]    

Ruilong Cai, The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China.

 
Abstract
 

Blends of polycarbonate (PC) and acrylonitrile-butadiene-styrene (ABS) were prepared and some mechanical, morphological properties and thermal stability were investigated. We selected the ratio of 80/20 to prepare PC/ABS alloys. Two kinds of compatibilizers, methacrylate-butadiene-styrene (MBS) and styrene-maleic anhydride (SMA) were used to improve the compatibility between PC and ABS. The results showed that SMA had no significant effect on the tensile strength of the blends while MBS decreased the tensile strength of blends a lot. Results of notched charpy impact strength tests showed that SMA increased the impact strength of blends more than MBS. The maximum increase was about 36.4 % when using 15wt% of SMA. Scanning electron microscopy micrographs showed that the particle size of ABS was decreased in the continuous phase of PC by using the compatibilizers. Moreover, differential scanning calorimetry (DSC) curves proved both MBS and SMA could make the glass transition temperature (Tg) of two phase close to each other. Finally, thermogravimetric tests showed that MBS and SMA had little effect on thermal stability of the PC/ABS blend.


Keywords
 

Polycarbonate, Acrylonitrile-Butadiene-Styrene, Blend, Compatibilizer


Reference
 
[01]    

Wu J S, Shen S C, Chang F C. Effect of rubber content in acrylonitrile-butadiene-styrene and additional rubber on the polymer blends of polycarbonate and acrylonitrile-butadiene-styrene [J]. Polymer journal, 1994, 26 (1): 33-42.

[02]    

Farzadfar A, Khorasani S N, Khalili S. Blends of recycled polycarbonate and acrylonitrile-butadiene-styrene: comparing the effect of reactive compatibilizers on mechanical and morphological properties [J]. Polymer International, 2014, 63(1): 145-150.

[03]    

Koning C, Van Duin M, Pagnoulle C, et al. Strategies for compatibilization of polymer blends[J], Progress in Polymer Science, 1998, 23(4): 707-757.

[04]    

Song Jian, Zhou Wenjun, Chen Ke, et al. Effects of Maleic Anhydride Graf ted Compatibil izer on PC/ ABS Blends[J]. Journal of Hangzhou Normal University, 2010, 9(2): 118-123.

[05]    

Quyang Xiaodong, Wu Fen. The application of new compatibilizer in PC/ABS alloly [J]. Engineering Plastics Application, 2003, 31(1): 9-12.

[06]    

Yang Yongbing, Miao Licheng, Zhou Rudong, et al. Research on high quality PC /ABS alloy[J]. Modern Chemical Industry, 2010, 30(11): 52-56.

[07]    

Greco R, Iavarone M. Influence of low molecular weight ABS species on properties of PC/ABS systems [J]. Polymer Engineering & Science, 2000, 40(7): 1701-1715.

[08]    

Robeson L M. Polymer blends [J]. Hanser, Munich, 2007: 109-210.

[09]    

Kim S J, Shin B S, Hong J L, et al. Reactive compatibilization of the PBT/EVA blend by maleic anhydride [J]. Polymer, 2001, 42(9): 4073-4080.

[10]    

Tjong S C. Meng, Y. Z. Effect of reactive compatibilizers on the mechanical properties of polycarbonate/poly (acrylonitrile-butadiene-styrene) blends [J]. European Polymer Journal, 2000, 36(1): 123-129.

[11]    

Zha L F, Wu W, Chen J F, e.t al. Toughening of polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS)blends by ethylenevinyl acetate-grafted maleic anhydride copolymer(EVA-g-MAH)and modified nano-CaCO3 [J]. Journal-Beijing Univerersity of Chamical Technology Natural Science Edition, 2007, 34 ( 4 ): 400-413.

[12]    

Balakrishnan S, Neelakantan N R. Mechanical properties of blends of polycarbonate with unmodified and maleic anhydride grafted ABS [J]. Polymer international, 1998, 45(4): 347-352.

[13]    

Zhang W, Yu Q. Study on Thermodynamic Miscibility of PC/ABS alloys[J]. Modern Plastics Progressing and Applications, 2005, 17(4) : 20-23.

[14]    

Chiang W Y, Tzeng G L. Effect of the compatibilizers on flame-retardant polycarbonate (PC)/acrylonitrile-butadiene-styrene (ABS) alloy [J]. Journal of applied polymer science, 1997, 65(4): 795-805.





 
  Join Us
 
  Join as Reviewer
 
  Join Editorial Board
 
share:
 
 
Submission
 
 
Membership