






Vol.2 , No. 1, Publication Date: Feb. 15, 2015, Page: 16-21
[1] | Esam A. Gomaa, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt. |
[2] | Rania R. Zaky, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt. |
[3] | Ahmed Fekri, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt. |
[4] | Mohamed A. Abdel-Fattah, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt. |
The molal solubility for nano and bulk (normal) lead bromide (LBr) in different percentages of dimethylformamide (DMF) and water were measured at 298.15, 303.15, 308.15 and 313.15K. From the molar solubilities for nano and bulk (LBr), the solvation parameters, like, activity coefficient, solubility product, free energy of solvation, enthalpy of solvation and entropy of solvation were estimated. All these solvation parameters were discussed and compared for both nano and bulk (LBr).
Keywords
Thermodynamics, Molar Solubility, Nano and Bulk Lead Bromide, Free Energy, Enthalpy, Entropy of Solvation, Mixed DMF - H2O Solvents
Reference
[01] | A. F. Hollemanm, E. Wiberg, Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5, (2001). |
[02] | David A. Wright and Pamela Welbourn, Environmenal toxicology, Cambridge University Press, UK (2002). |
[03] | Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0487-3. |
[04] | Michael J. Dagani, Henry J. Barda, Theodore J. Benya, David C. Sanders "Bromine Compounds" in Ullmann's Encyclopedia of Industrial Chemistry" Wiley-VCH, Weinheim, 2000. doi:10.1002/14356007. |
[05] | Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0080379419. |
[06] | S. Budavari (Ed.), The Merck Index: An Encyclopedia of Chemicals, Drugs and Biologicals, 12th ed., Merck Co. Inc., Whitehouse Station, NJ, 1996. |
[07] | A.E. Williams, in: H.F. Mark, D.F. Othmer, C.G. Overberger, G.T. Seaborg (Eds.), Kirk-Othmer Encyclopedia of Chemical Technology, vol. 3, 3rd ed., Wiley, New York, 1978, pp. 778–792. |
[08] | J. L. Opgrande, C. J. Dobratz, E. E. Brown, J. C. Liang, G. S. Conn, J. Wirth, J. Shelton, in: J. I. Kroschwitz, M. Howe-Grant (Eds.), Kirk-Othmer Encyclopedia of Chemical Technology, vol. 4, 4th ed., Wiley, New York, 1992, pp. 103–115. |
[09] | C.M. Park, R.J. Shechan, in: B. Elvers, S. Hawkins, G. Schultz (Eds.), Ullmann’s Encyclopedia of Industrial Chemistry, vol. 18, fifth rev. ed, Basel, 1991, pp. 991–1043. |
[10] | D. E. Read, C. B. Purves, J. Am. Chem. Soc. 74 (1952) 116–119. |
[11] | E. E. Schrier, M. Pottle, H.A. Scheraga, J. Am. Chem. Soc. 86 (1964) 3444–3449. |
[12] | E. Suzuki, Y. Taniguchi, T. Watanabe, J. Phys. Chem. 77 (1973) 1918–1922. |
[13] | K. Yamamoto, N. Nishi, J. Am. Chem. Soc. 112 (1990) 549–558. |
[14] | P. Debye, E. Hückel, Z. Phys. 24 (1923)185, 305. |
[15] | Esam A. Gomaa and R. M. Galal, Basic Sciences of Medicine, 1(2), (2012), 1-5. |
[16] | Esam A. Gomaa, Physics and Chemistry of Liquids, 50(2012)279-283. |
[17] | Esam A. Gomaa, International Journal of Materials and Chemisty, 2(1), (2012)16-18. |
[18] | Esam A. Gomaa, American Journal of Environmental Engineering, 2(3), (2012)54-57. |
[19] | Esam A. Gomaa. American Journal of Polymer Science, 2(3), (2012), 35-38. |
[20] | Esam A.Gomaa. Eur. Chem. Bull., 1(2013) 259-261. |
[21] | Esam A.Gomaa, Elsayed abou Elleef and E.A.Mahmoud , Eur . Chem. Bull, 2(2013), 732-735. |
[22] | Esam A Gomaa and Elsayed M.Abou Elleef, American Chemical Science Journal, 3(2013) , 489-499. |
[23] | Esam A. Gomaa, Elsayed M. Abou Elleef, Science and Technology, 3(2013)118-122. |
[24] | Esam A Gomaa and M. G. Abdel Razek, International Research Journal of Pure and Applied Chemistry, 3 (2013)320-329 |
[25] | Esam A. Goma, International Journal of Theoretical and Mathematical Physcics, 3(2013)151-154. |
[26] | Esam A. Gomaa and B. A. Al Jahadali, Education., 2(3),(2012)37-40. |
[27] | Esam A Gomaa, American Journal of Biochemistry, 2(3), 92012),25-28. |
[28] | Esam A. Gomaa, Food and Public Health, 2(3), 2012, 65-68. |
[29] | Esam A. Gomaa, Global Advanced Research Journal of Chemistry and Material Science, 1(2012)35-38. |
[30] | Esam A. Gomaa, Frontiers in Science, 2(2012)24-27. |
[31] | Esam A Gomaa, Elsayed M. Abou Elleef, E. T. Helmy and Sh. M. Defrawy, Southern Journal of Chemistry, 21(2013)1-10. |
[32] | E. A. Gomaa, K. M. Ibrahim, N. M. Hassan, Frontiers in Science,2(2012) 76-85. |
[33] | E. A. Gomaa, K. M. Ibrahim and N. M. Hassan, The International Journal of Engineering and Science (IJES), 3 (20144) 44-51. |
[34] | E A. Gomaa, H. M. Abu El-Nader and Sh. E. Rashed, The International Journal of Engineering and Science (IJES), 3(2014) 64-73. |
[35] | E. A. Gomaa, K. M. Ibrahim and N. M. Hassan, Research and Reviews: Journal of Chemistry, 3(2014) 47-55. |
[36] | Esam A. Gomaa and Elsayed M. Abou Elleef, Thermal and Power engineering, 3 (2014), 222-226. |
[37] | Esam A Gomaa, Elsayed M. Abou Elleef, Elsayed T. Helmy , Research and reviews: Journal of Chemistry, 3(2014)22-27. |
[38] | Esam A. Gomaa,.Science and Technology,3(2013)123-126. |
[39] | E. A. Gomaa, Research and Reviews: Journal of Chemistry, 3(2014),28-37. |
[40] | E. A. Gomaa, A. H. El-Askalany and M. N. H. Moussa, Rev. Roum. Chim, 32 (1987)243. |
[41] | Esam A Gomaa, Thermochimica Acta, 128 (1988) 99. |
[42] | E. A. Gomaa, Indian J. of Tech., 24 (1986) 725. |
[43] | Esam A. Gomaa, Thermochimica Acta, 142 (1989) 19. |
[44] | Esam A. Gomaa, Croatica Chimica Acta, 62 (1989) 475. |
[45] | Esam A. Gomaa, Thermochimica Acta, 147 (1989) 313. |
[46] | E. A. Gomaa, A. M. Shallapy and M. N. H. Moussa, J. Indian Chem. Soc., 68(1991)339. |
[47] | E. A. Gomaa, A. M. Shallapy and M. N. H. Moussa, Asian J. of Chem., 4(1992)518. |
[48] | H.M. Abu El-Nader and E. A. Gomaa, Mansoura Science Bulletin. (A Chem.) Vol .23 (1) July 1996. |
[49] | J. I. Kim, A. Cecal, H. J. Born, and E. A. Gomaa, Z. Physik Chemic, Neue Folge 110, 209 (1978). |
[50] | J. I. Kim and E. A. Gomaa, Bull. Soci. Chim. Belg., 90 (1981) 391. |
[51] | E. A. Gomaa, A. A. El-Khouly and M. A. Mousa, Indian Journal of Chemistry, 23 ((1984) 1033. |
[52] | E. A. Gomaa, M. A. Mousa and A. A. El-Khouly, Thermochimica Acta, 86 (1985) 351. |
[53] | E. A. Gomaa, M. A. Mousa and A. A. El-Khouly, Thermochimica Acta, 89 (1985) 133. |
[54] | Esam A.Gomaa, Thermochimica Acta, 91 (1985) 235. |
[55] | Esam A. Gomaa, Thermochimica acta, 128 (1988) 287. |
[56] | Esam A. Gomaa, Thermochimica Acta, 140 (1989) 7. |
[57] | Esam A. Gomaa, Bull. Soc. Chim. Fr. 5 (1989) 620. |
[58] | Esam A. Gomaa, Bull. Soc. Chim. Fr., 5 (1989) 623. |
[59] | Esam A. Gomaa, Thermochimica acta, 152 (1989) 371. |
[60] | Esam A. Gomaa, Thermochimica Acta, 156 (1989) 91. |
[61] | I. S. Shehatta, A. H. El-Askalany and E. A. Gomaa, Thermochimica Acta, 219(1993)65. |
[62] | E. A. Gomaa and G. Begheit, Asian Journal of Chemistry, 2(1990)444. |
[63] | A. A. El-Khouly, E. A. Gomaa, and S. Abou-El-Leef, Bull. Electrochem 19, 153 (2003). |
[64] | A. A. El-Khouly, E. A. Gomaa, and S. Abou El-Leef, Bull. Electrochem 19, 193 (2003). |
[65] | M. A. Hamada, E. A. Gomaa and N. A. El-Shishtawi, International Journal of Optoelectronic Enegineering, 1(2012)1-3. |
[66] | Kamal M. Ibrahim, Esam A. Gomaa, Rania R. Zaky and M. N. Abdel El-Hady, American Journal of Chemistry, 2(2012) 23-26. |
[67] | A. A. El-Khouly, E. A. Gomaa and S. E. Salem, Southern Brazilian Journal of Chemistry, vol. 20 (2012) 43-50. |
[68] | E. A. Gomaa and B. A. M. Al –Jahdali, American Journal of Environmrntal Engineering, 2(2012) 6-12. |
[69] | S. L. Oswal, J. S. Desai, S. P. Ijardar, and D. M. Jain, J. Mol. Liquids 144, 108 (2009). |
[70] | D. Bobicz, W. Grzybkowski, and A. Lwandowski, J. Mol. Liquids 105, 93 (2003). |
[71] | Y. Marcus. The Properties of Solvents (Wiley, London, 1998). |
[72] | E. A. Gomaa, A. H. El-Askalany, M. N. H. Moussa, Asian Journal of Chemistry,4(1992)553. |
[73] | Esam A. Gomaa, Rev. Roum. de Chimie,36(1991)11. |
[74] | Esam A. Gomaa, Journal of King Saud University, 3(1), 1991, 1411. |
[75] | Esam A. Gomaa, Oriental Journal of Chemistry, 6(1990)12. |
[76] | E. A. Gomaa, M. A. Hamada and R. Galal, Avances en Quimica, 5(2), 117-121(2010). |
[77] | Esam a. Gomaa, Analele Uni. din Bucuresti-Chimie, vol.19 no1, pag.45-48(2010). |
[78] | Nagah A. El-Shishtawi, Maany A. Hamada and Esam A. Gomaa, Physical Chemistry, 1(1), (2011), 14-16. |
[79] | E. A. Gomaa and B. A. M. Al Jahdali, American Journal of Condenesed Matter Physics, 2(1),(2012),16-21. |