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Vol.2 , No. 1, Publication Date: Jan. 28, 2015, Page: 1-11
 with N,-Bezylidene-4-Chlorobenzo-Hydrazide (LB) in Mixed EtOH-H2O Solvents&description=Characterization of nano calcium acetate (CAc) is done by transmission electron microscopy (TEM), atomic force microscope (AFM) and x-ray diffraction. The thermodynamic parameters for association and complex formation for both bulk CAc (normal) and nano- CAc were evaluated by using condutometric measurements. The association thermodynamic parameters of both bulk -CAc and nano-CAc salts in ethanol (EtOH) + H2O were calculated in presence of N,-bezylidene-4-chlorobenzohydrazide (LB), non isothermally at different temperatures, 293.15, 298.15, 303.15 and 308.15 K. The thermodynamic solvation parameters for both types of CAc were compared.&picture=http://www.aascit.org/aascit/decorators/img/journal/916.jpg)
| [1] | Esam A. Gomaa, Manoura University Nanotechnology Center, Mansoura, Egypt; Faculty of Science, Chemistry Department, Mansoura University, Mansoura, Egypt. |
| [2] | Abdel Moniem H. El Askalany, Faculty of Science, Chemistry Department, Mansoura University, Mansoura, Egypt. |
| [3] | Kamal M. Ibrahim, Faculty of Science, Chemistry Department, Mansoura University, Mansoura, Egypt. |
| [4] | Rania M. Galal, Faculty of Science, Chemistry Department, Mansoura University, Mansoura, Egypt. |
| [5] | Maany A. Hamada, Faculty of Science, Chemistry Department, Mansoura University, Mansoura, Egypt. |
Characterization of nano calcium acetate (CAc) is done by transmission electron microscopy (TEM), atomic force microscope (AFM) and x-ray diffraction. The thermodynamic parameters for association and complex formation for both bulk CAc (normal) and nano- CAc were evaluated by using condutometric measurements. The association thermodynamic parameters of both bulk -CAc and nano-CAc salts in ethanol (EtOH) + H2O were calculated in presence of N,-bezylidene-4-chlorobenzohydrazide (LB), non isothermally at different temperatures, 293.15, 298.15, 303.15 and 308.15 K. The thermodynamic solvation parameters for both types of CAc were compared.
Keywords
Thermodynamics, Nano Calcium Acetate, Free Energy, Enthalpy, Entropy, Association, Complex Formation, Mixed EtOH–H2O Solvents
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