ISSN: 2375-3870
International Journal of Modern Physics and Application  
Manuscript Information
 
 
An Experimental Study on Degreasing of Zircaloy Tubes and Optimization of Process Parameters
International Journal of Modern Physics and Application
Vol.6 , No. 1, Publication Date: May 30, 2019, Page: 1-8
1811 Views Since May 30, 2019, 667 Downloads Since May 30, 2019
 
 
Authors
 
[1]    

Pankaj Kumar Battabyal, Nuclear Fuel Complex, Hyderabad, India.

[2]    

Debapriya Mandal, Alkali Material & Metal Division, Bhabha Atomic Research Centre, Mumbai, India.

 
Abstract
 

In the reducing operation of zircaloy tubes, lubricants are applied on both inner and outer surfaces, which must be cleaned before vacuum annealing of the tubes. Degreasing is a vital unit operation in production of zircaloy tubes, which are used as cladding of fuels for nuclear power plants. The rate limiting operation of the multistage degreasing of zircaloy tubes is the treatment with hot alkali solution. Different lubricating oils have been used in the tube reducing mill. A detailed study was felt necessary, since it is the rate determining step in the degreasing operation. In this operation five different chemicals are used sequentially for saponification, chelation, emulsification, deflocculating and wetting. Selection of proper physico-chemical parameters may reduce the soaking time. The effect of the concentration of different chemicals and process parameters on the cleansing action was studied with an objective to find a cost effective optimum composition for degreasing operation. The detailed process of degreasing, parametric study, results, optimization of process parameters and conclusions are discussed in this paper.


Keywords
 

Zircaloy, Degreasing, Nuclear, Fuel Tubes, Power Plants, Cleansing Solution, Alkaline


Reference
 
[01]    

Ko Buijs, Innomet B. V., Zirconium facts at your fingertips, Stainless Steel World, September (2008), 1- 4.

[02]    

Walter J. Weber, Han S. Kim, Removal of greases and lubricating oils from metal parts of machinery processes by subcritical water treatment, J. of Supercritical Fluids 80 (2013) 30–37.

[03]    

Nilesh S. Dumore, Mausumi Mukhopadhyay, Removal of oil and grease using immobilized triacyl glycerin lipase, International Bio-deterioration & Biodegradation 68 (2012) 65–70, 2013.

[04]    

R. M. Mortier, S. T. Orszulik (Chemistry), Technology of Lubricants, VCH Publishers, Inc., New York, 1992.

[05]    

M. N. V. Prasad (Ed.), Metals in the Environment: Analysis by biodiversity, Marcel Dekker Inc., New York, 2001.

[06]    

K. Schumann, K. Siekmann, Soaps, Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.

[07]    

Rosen MJ and Kunjappu, Surfactants and Interfacial Phenomena, 4th ed., Hoboken, New Jersey: John Wiley & Sons, (1-118-22902-9), 2012.

[08]    

Robert Berger, Ulf Bexell, Nils Stavlid, T. Mikael Grehk, The influence of alkali-degreasing on the chemical composition of hot-dip galvanized steel surfaces, 2010.

[09]    

A. D. McNaught, A. Wilkinson, Definition of electro kinetic potential in IUPAC (Compendium of Chemical Terminology), 2nd ed. (the Gold Book), 2006.

[10]    

USEPA, Guide to Cleaner Technologies, Cleaning and Degreasing Process Changes, Office of Research and Development, USEPA, Washington, DC, (EPA/625/R-93/017), 1994.





 
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