ISSN Print: 2381-1072  ISSN Online: 2381-1080
Engineering and Technology  
Manuscript Information
 
 
Non Isothermal Thermodynamic Interaction Parameters of Bulk and Nano CuSO4 with Bromophenol Blue (BPB)
Engineering and Technology
Vol.2 , No. 2, Publication Date: Apr. 10, 2015, Page: 74-80
1491 Views Since April 10, 2015, 1125 Downloads Since Apr. 12, 2015
 
 
Authors
 
[1]    

Mohamed N. H. Hamed, Faculty of Education, Chemistry Department, Ain Shams University, Roxy, Cairo, Egypt.

[2]    

Esam A. Gomaa, Faculty of Science, Chemistry Department, Mansoura University, Mansoura, Egypt.

[3]    

Sameh G. Sanad, Faculty of Education, Chemistry Department, Ain Shams University, Roxy, Cairo, Egypt.

 
Abstract
 

Characterization of the prepared nanoCuSO4 is done by using transmission electron microscopy (TEM) and its thermodynamic parameters were determined using conductometric measurements. The association and complex formation parameters for both bulk (normal) and nano-CuSO4 salts in dimethylformamide (DMF) and water mixtures were calculated in presence of bromophenol blue (BPB), non isothermally at different temperatures, 292.15 , 303.15 , 308.15 and 313.15K.The thermodynamics of the complexation reactions for bulk and nano CuSO4 salts were compared.


Keywords
 

Thermodynamics, Molar Conductance, Nano Copper Sulfate and Bulk Copper Sulfate, Bromophenol Blue and Mixed


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