ISSN Print: 2381-0998  ISSN Online: 2381-1005
Journal of Materials Sciences and Applications  
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Development of New Alternative Environmental-Friendly Passivatorfor Zinc Coated Sheets
Journal of Materials Sciences and Applications
Vol.3 , No. 4, Publication Date: Aug. 29, 2017, Page: 58-65
235 Views Since August 29, 2017, 395 Downloads Since Aug. 29, 2017
 
 
Authors
 
[1]    

Saravanan Pandurangan, R&D Center for Iron and Steel, Steel Authority of India Limited, Ranchi, India.

[2]    

Srikanti Srikanth, R&D Center for Iron and Steel, Steel Authority of India Limited, Ranchi, India.

[3]    

Santhosh kumar, R&D Center for Iron and Steel, Steel Authority of India Limited, Ranchi, India.

 
Abstract
 

Commercially available Tri-chromium and chrome-free passivator were evaluated with respect to their white rust resistance to the salt environment. The study also focused to evolve new environmental-friendly passivator for zinc-coated sheets. The corrosion behavior and mechanism of passivated samples are studised by electrochemical techniques. From electrochemical corrosion studies, the corrosion rates of commercial available chrome free passivator, tannic acid (t) and cerium+tannic acid passivated samples were identified as (2 to 3), 1.4, and 0.4 mpy, respectively. Cerium+tannic acid passivated samples exhibited a better corrosion resistance than commercial chrome-free or tannic acid passivated samples.


Keywords
 

Tri-chromium Passivator, Chrome-free Passivator, Zinc Coated Sheets Corrosion, Cerium and Tannic Acid


Reference
 
[01]    

A. J. Stavros: “Continuous Hot Dip Coatings”, Metals Handbook, American Soc. of Metals, 13, 432.

[02]    

Takao O., Surface Treatment Agent for Zinciferous-Plated Steel, USA patent, 5846342, 1998.

[03]    

T. Biestek and J. Weber: Conversion Coatings, Portcullis Press Limited- Redhill, Surrey, 1st Edition, 1976.

[04]    

Galvatech ’04, 6th Intl. Conf. on Zinc and Zinc Alloy Coated Sheet Steels, April 4-7 2004, Chicago, USA.

[05]    

G. D. Wilcox and D. R. Gabe: “Chemical Molybdate Conversion Treatments for Zinc”, Metal Finishing, September 1998, 71.

[06]    

Lunder O., Walmsley J. C., Mack P., and Nisancioglu K., Formation and characterisation of a chromate conversion coating on AA6060 aluminium, Corros. Sci., 2005, 47, 1604.

[07]    

C. Barnes, JJD Ward, “Non-chromate passivation treatments for zinc”, TIMF, 1982, 60, 56.

[08]    

W. V. Ooij, M. Stacy, V. Palanivel, A. Lamar and D. Zhu: “The Use of Organofunctional Silanes as a Major Constituent in Organic Coatings for enhanced Corrosion Protection”, 13th IFHTSE Congress/International Surface Engineering Congress, Columbus, Ohio, 7-10 Oct 2002, pp1-9.

[09]    

Hao J. J., An C. Q., and Mou S. H., Advances in research on unchromium passivation of galvanized zinc layer, Mater. Rev., 2003, 9 (17): 19.

[10]    

Tang T. and Beth-Nielsen G., Molybdate-based alternatives to chromating as a passivation treatment for zinc, Plat. Surf. Finish., 1994, 18 (11): 20.

[11]    

Bexell U. and Grehk T. M., A corrosion study of hot-dip galvanized steel sheet pre-treated with γ-mercaptopropyltrimethoxysilane, Surf. Coat. Technol., 2007, 201: 4734.

[12]    

Deflorian F., Rossi S., Fedrizzi L., and Bonora P. L., EIS study of organic coating on zinc surface pretreated with environmentally friendly products, Prog. Org. Coat., 2005, 52: 271.

[13]    

D. D. N. Singh and Rita Ghosh, “Molybdenum–phosphorus compounds based passivator to control corrosion of hot dip galvanized coated rebars exposed in simulated concrete pore solution”, Volume 202, Issue 19, 25 June 2008, Pages 4687–4701.

[14]    

Aramaki K. The effect of medication with hydrogen peroxide on a hydrated cerium (III) oxide layer for protection of zinc against corrosion in 0.5 M NaCl, Corros. Sci., 2006, 48 (16): 766.

[15]    

Aramaki K., The inhibition effects of chromate-free, anion inhibitors on corrosion of zinc in aerated 0.5 M NaCl, Corros. Sci., 2001, 43: 591.

[16]    

Yajuan Liu, Jinyong Xu, Ying Gao, Ye Yuan, Cheng Gao, “Influences of Additive on the Formation and Corrosion Resistance of Micro-arc Oxidation Ceramic coatings on Aluminum Alloy”, Physics Procedia, Volume 32, 2012, Pages 107-112.

[17]    

J. R. Scully, N. Tailleart, and F. Presuel-Moreno, “Rare Earth-Based Corrosion Inhibitors- Chapter-9- Tunable multifunctional corrosion-resistant metallic coatings containing rare earth elements”, Edited by: M. Forsyth and B. Hinton, A volume in Woodhead Publishing Series in Metals and Surface Engineering 2014, Pages 267–290.

[18]    

LIU Guangming, YU Fei, YANG Liu, TIAN Jihong, and DU Nan, “Cerium-tannic acid passivation treatment on galvanized steel”, RARE METALS, 2009, 28, (3) 284.

[19]    

M. A. Deyab, Rachid Ouarsal, A. M. Al-Sabagh, Mohammed Lachkar, B. El Bali, “Enhancement of corrosion protection performance of epoxy coating by introducing new hydrogen phosphate compound”, Progress in Organic Coatings, Volume 107, June 2017, Pages 37-42.

[20]    

Sepideh Pourhashem, Alimorad Rashidi, Mohammad Reza Vaezi, Mohammad Reza Bagherzadeh, “Excellent corrosion protection performance of epoxy composite coatings filled with amino-silane functionalized graphene oxide”, Surface and Coatings Technology, Volume 317, 15 May 2017, Pages 1-9.





 
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