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Heteroassociation of Dyes in an Aqueous Solution: the Interaction of Cyanine Cations with 3',3'',5',5''-Tetrabromo-m-cresolsulfonephthalein Anions

International Journal of Chemical and Biomedical Science
Vol.3 , No. 6, Publication Date: Dec. 29, 2017, Page: 79-84

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Authors

[1]	Shapovalov Serghey, V. N. Karazin Kharkiv National University, Kharkiv, Ukraine.

Abstract

Heteroassociation of cationic cyanines (quinaldine red, quinaldine blue) with 3',3'',5',5''-tetrabromo-m-cresolsulfonephthalein anions has been studied experimentally and theoretically. The values of the equilibrium association constants in the aqueous solution are determined spectrophotometrically. Geometric and energy characteristics of associates are calculated with the help of AM1 method. The effect of ionic surfactants on associates has been studied.

Keywords

Heteroassociation, Dye, Absorption Spectra, Solution, Enthalpy of Formation, AM1 Method, Surfactants

Reference

[01]	Ishchenko A. A., Shapovalov S. A. (2004) Heterogeneous association of the ions of dyes in solutions (review). J. Appl. Spectrosc. (Belarus) 71: 605-629.
[02]	Shapovalov S. A., Koval V. L., Chernaya T. A., Pereversev A. Yu., Derevyanko N. A., Ishchenko A. A., Mchedlov-Petrossyan N. O. (2005) Association of indopolycarbocyanine cations with anions of sulfphonephthalein and xanthene dyes. J. Braz. Chem. Soc. 16: 232-240.
[03]	Steinberg I. M., Steinberg M. D. (2009) Radio-frequency tag with optoelectronic interface for distributed wireless chemical and biological sensor applications. Sensors and Actuators. B: Chemical 138: 120-125.
[04]	Oberg K. I., Hodyss R., Beauchamp J. L. (2006) Simple optical sensor for amine vapors based on dyed silica microspheres. Sensors and Actuators. B: Chemical 115: 79-85.
[05]	Kim J. A., Cho K., Shin M. S., Lee W. G., Jung N., Chung C., Chang J. K. (2008) A novel electroporation method using a capillary and wire-type electrode. Biosensors and Bioelectronics 23: 1353-1360.
[06]	Guillén M. G., Gámez F., Lopes-Costa T., Cabanillas-González J., Pedrosa J. M. (2016) A fluorescence gas sensor based on Förster resonance energy transfer between polyfluorene and bromocresol green assembled in thin films. Sensors and Actuators B: Chemical 236: 136-143.
[07]	Zhuk Y. N., Vasyuk S. O. (2016) Spectrophotometric determination of betaxolol in pure form and pharmaceuticals. The Pharma Innovation J. (Ukr.) 5: 31-33.
[08]	Sayanna, Jyothi M., Veeraiah T., Venkata Ramana Reddy CH. (2016) Spectrophotometric determination of ethambutol in pure and pharmaceutical forms using triphenyl methane dyes. Internat. J. Pharmaceut. Sci. Res. 7: 4191-4199.
[09]	Chennaiah M. (2016) Extractive spectrophotometric methods for determination of prasugrel hydrochloride in pharmaceutical formulations using some acidic triphenylmethane dyes. Asian J. Res. Chem. 9: 373-377.
[10]	Ali E. A., Adawy A. M., El-Shahat M. F., Amin A. S. (2016) Simple spectrophotometric methods for determination of fluoxetine and clomipramine hydrochlorides in dosage forms and in some post-mortem biological fluids samples. Egypt. J. Forensic Sci. 6: 370-380.
[11]	Satya T., Yadav S. S. G. K., Ramanaiah S., Chakravarthy I. E. (2016) Spectrophotometric determination of paliperidone palmitate in tablets. Ind. J. Advan. Chem. Sci. 4: 191-194.
[12]	Amin A. S., Salah H. M., Ragab G. H., Kamel I. S. (2015) Sensitive spectrophotometric and conductometric methods for determination of candesartan using bromocresol green and bromocresol purple by ion-pair complex formation. J. Chem. Mater. Res. 2: 42-48.
[13]	Swamy N., Basavaiah K. (2013) Selective and sensitive assay of mebendazole in pharmaceuticals using bromocresol green by spectrophotometry. Thai J. Pharm. Sci. 37: 171-185.
[14]	Shapovalov S. A. (2008) Evaluation of the stability of dye heteroassociates formed in aqueous solutions. Russ. J. Phys. Chem. A. 82: 1499-1505.
[15]	Shapovalov S. A., Kiseleva Ya. S. (2008) The association of cyanine dye cations with phenol red anions in aqueous solutions. Russ. J. Phys. Chem. A. 82: 972-977.
[16]	Kolthoff I. M., Chantooni M. K., Browmik S. (1967) Acid-base indicator constants in acetonitrile. Analyt. Chem. 39: 315-320.
[17]	Kolthoff I. M., Browmik S., Chantooni M. K. (1966) Acid-base indicator properties of sulfonephthaleins and benzeins in acetonitrile. Proc. Nat. Acad. Sci. (USA) 56: 1370-1376.
[18]	Shapovalov S. A., Samoilov E. A. (2008) Regularities of homo- and heteroassociation of the pinacyanol cation in aqueous solution. Russ. Chem. Bull. (Internat. Ed.) 57: 1405-1415.